Kelvin

Kelvin hero

The Unit – kelvin, K (kelvin)

The SI unit of temperature, the kelvin (K), is named after the Belfast-born engineer and physicist William Thomson, who became Lord Kelvin in 1892 as a recognition of his achievements in thermodynamics.

The kelvin is currently defined in terms of the triple point of water – a unique temperature at which the three phases of water (solid, liquid, and vapour) co-exist in equilibrium. Since 1954, the triple point of water has been used as the fundamental fixed point against which other temperatures are measured. The formal definition of the kelvin is:

“The kelvin, unit of thermodynamic temperature, is the fraction 1/273.16 of the thermodynamic temperature of the triple point of water.”

In principle, temperature is based on a thermodynamic concept that characterises the average kinetic energy of small particles in thermal equilibrium. The magnitude of the unit is equivalent to a definition of Boltzmann’s constant, k, and this constant turns up in all physical formulae that describe the physical effects caused by temperature. One such relationship is Boyle’s law:

 PV = nRT ,

which relates the pressure and volume of n atoms of an ideal gas to its temperature. Unfortunately, neither gas thermometers, which exploit Boyle’s Law, nor most other thermodynamic thermometers, are sufficiently small or convenient to be of practical use, and these thermometers have only recently become accurate enough to satisfy the needs of science and industry. The best gas thermometer experiments take several months of work, and a million dollars-worth of equipment, to measure a single temperature.

Instead of a true metric temperature scale (thermodynamic temperature), the General Conference on Weights and Measures (CGPM) has defined a more practical scale based on defined temperatures for the melting, freezing, and triple points of pure substances. In addition, they approved interpolating thermometers to define the temperatures that fall between these points. This scale, which is reproducible to about 1 mK for temperatures below a few hundred degrees Celsius, is updated approximately every 20 years. The current version is called the International Temperature Scale of 1990, or ITS-90(external link). Temperatures on ITS-90 can be expressed in either kelvin or degrees Celsius, and are sometimes distinguished using an upper-case T and lower-case t, respectively. The two units have the same size (so that temperature differences or intervals are equal in both units), but values are offset from each other:

 T / K = t/°C +273.15 .       

Differences between the ITS-90 temperature scale and thermodynamic temperature can be found here(external link). As of World Metrology Day 2019 (20 May), thermodynamic temperature will be defined in terms of Boltzmann’s constant instead of the triple point of water. This will allow for the future development of technologies that may improve the accuracy of temperature measurement, free of any limitations arising from the use of triple point of water cells. However, the triple point of water is likely to remain the fundamental reference for the foreseeable future, and ITS-90 will remain in force for many decades to come.

 

ITS-90 temperature scale showing the fixed points, the interpolating thermometer types, and ranges over which different interpolating equations are used. MSL covers ranges from the argon point to the copper point.

Technical Capability

We are leading experts in contact thermometry, radiation thermometry, and humidity, and provide a wide range of temperature-related measurement and consultancy services. We can help you to understand limitations in the accuracy of industrial thermometers, identify errors in applications of radiation thermometry, or improve the accuracy of humidity measurements.

We provide a calibration service covering the temperature ranges –190 °C to 550 °C for contact thermometry and –25 °C to 1100 °C for radiation thermometry, and the relative humidity range 10 % RH to 95 % RH from –60 °C to 70 °C (see here for our Temperature and Humidity calibration services)

Our Research

Our research covers a wide range of topics, from difficult industrial measurements, sensor characterisation, new calibration techniques and instruments, physical modelling and uncertainty analysis, to the fundamental definitions of the standards. Research topics include:

  • Reflection errors in radiation thermometry, for applications in the petrochemical, metal processing, and food industries. This includes the effects of emissivity and the bidirectional reflectance distribution function (BRDF) of industrial materials.
  • Limitations in the accuracy of industrial thermometers – immersion effects, hysteresis, and ageing effects in thermocouples.
  • Using thermocouple homogeneity scanning to develop an understanding of the damage mechanisms in thermocouples, and to develop new stable rare metal reference thermocouples.
  • Calibration equations and propagation of uncertainty for standard platinum resistance thermometers (SPRTs), radiation thermometers, and humidity sensors.
  • Propagation of uncertainty and covariance, using generalised least squares, in the IAPWS-95 thermodynamic equations of state for pure water and associated properties.
  • Development of a Resistance Bridge Calibrator (RBC) based on a combinatorial technique using four stable base resistors.
  • Size-of-source effect (SSE) and non-linearity in radiation thermometers.
  • Effects of isotopic composition and glass dissolution on the triple point of water.
  • New definition of relative humidity based on fugacity.
  • Use of double-wavelength radiation thermometry to measure thermodynamic temperature.
  • Measurement of Boltzmann’s constant using Johnson noise thermometry.

Relevant Publications

Jifeng Qu, Samuel P Benz, Kevin Coakley, Horst Rogalla, Weston L Tew, Rod White, Kunli Zhou, Zhenyu Zhou, “An improved electronic determination of the Boltzmann constant by Johnson noise thermometry”, Metrologia, 54, 549–558, 2017.

B Fellmuth, J Fischer, G Machin, SPicard, P P M Steur, O Tamura, D R White, H Yoon, “The kelvin redefinition and its Mise en Pratique”, Philosophical Transactions of the Royal Society A. Mathematical, Physical and Engineering Sciences, 374, article no. 20150037, 2016.

R Feistel, R Wielgosz, S A Bell, M F Camões, J R Cooper, P Dexter, A G Dickson, P Fisicaro, A H Harvey, M Heinonen, O Hellmuth, H-J Kretzschmar, J W Lovell-Smith, T J McDougall, R Pawlowicz, P Ridout, S Seitz, P Spitzer, D Stoica, H Wolf, “Metrological challenges for measurements of key climatological observables: oceanic salinity and pH, and atmospheric humidity. Part 1: overview”, Metrologia, 53, R1–R11, 2016.

J W Lovell-Smith, R Feistel, A H Harvey, O Hellmuth, S A Bell, M Heinonen, J R Cooper, “Metrological challenges for measurements of key climatological observables. Part 4: atmospheric relative humidity”, Metrologia, 53, R40–R59, 2016.

D R White, “Some mathematical properties of the ITS-90”, in Temperature: Its Measurement and Control in Science and Industry, Vol. 8, edited by C W Meyer, AIP Conference Proceedings, Melville, New York, 81–88, 2013.

P Saunders, “Uncertainties in the realisation of thermodynamic temperature above the silver point”, International Journal of Thermophysics, 32, 26–44, 2011.

G Machin, P Bloembergen, K Anhalt, J Hartmann, M Sadli, P Saunders, E Woolliams, Y Yamada, H Yoon, "Practical implementation of the Mise en Pratique for the definition of the kelvin above the silver point", International Journal of Thermophysics, 31, 1779–1788, 2010.

D R White, W L Tew, “Improved estimates of the isotopic correction constants for the triple point of water”, International Journal of Thermophysics, 31, 1644–1653, 2010.

D R White, M Ballico, D del Campo, S Duris, E Filipe, “Uncertainties in the realization of the SPRT sub-ranges of the ITS-90”, International Journal of Thermophysics, 28, 1868–1881, 2007.

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